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May,
2001
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Volume
1, No. 2
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Inside
this Newsletter
1.
Chlorine is chlorine is chlorine
2.Sodium
Hypochlorite Stability
3.
Water quality & piping
4.
On line
5.
Thought of the month
6.
Anyone know the answers?
7.
Fe & Mn reality check
8.
News from over there
9.
All phosphates are the same!
10.
The Bidding Process
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Chlorine
is chlorine is chlorine
All forms
of chlorine used for drinking water disinfection (whether
gas, on site generation, sodium hypochlorite, calcium hypochlorite,
etc.) result in two main chemical fractions--the more active
hypochlorous acid ion (HOCl-) and the less active hypochlorite
ion (ClO-). It is important to note that hypochlorous acid
ion is the most effective disinfectant of all the chlorine
residual fractions. This simply is due to the relative ease
by which the hypochlorous acid ion can penetrate bacteria
cell walls. In other words, of all chlorine fractions, nothing
kills bacteria better and quicker than the hypochlorous acid
ion. In order to produce the greatest proportion of hypochlorous
acid ion in drinking water supplies, it is necessary to take
a very close look at pH effects on each main fraction.
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solution concentration
5000 mg/l
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pH
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%Cl2
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%HOCl-
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%OCl-
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6.5
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.0063
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92.28
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7.71
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7.0
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.0017
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79.10
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20.89
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7.5
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.0004
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54.84
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45.21
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8.0
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.0001
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27.46
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72.54
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8.5
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.0000
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10.69
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89.31
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9.0
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.0000
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3.65
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96.35
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solution concentration
7000 mg/l
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pH
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%Cl2
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%HOCl-
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%OCl-
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6.5
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.0088
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92.28
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7.71
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7.0
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.0024
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79.10
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20.89
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7.5
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.0004
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54.49
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45.21
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8.0
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.0001
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27.46
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72.54
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8.5
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.0000
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10.69
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89.30
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9.0
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.0000
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3.65
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96.35
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solution concentration
10,000 mg/l
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pH
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%Cl2
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%HOCl-
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%OCl-
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6.5
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.0126
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92.28
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7.71
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7.0
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.0034
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79.10
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20.89
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7.5
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.0007
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54.49
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45.51
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8.0
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.0001
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27.46
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72.54
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8.5
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.0000
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10.69
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89.30
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9.0
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.0000
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3.65
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96.35
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Clearly
seen, lowering finished pH raises active hypochlorous acid
ion levels. Is it no wonder that systems running at higher
pH’s vie for chlorine disinfection alternatives (ozone, chlorine
dioxide, chloramines, UV, etc.). Would it not be better, much
cheaper, and far less labor intensive to simply lower finished
water pH to 6.5-7.0 maximizing hypochlorous acid ion concentration...given
appropriate corrosion control can be maintained? Of course
it would.
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Aqua
Smart Inc. 4445
Commerce Drive SW, Suite A4, Atlanta, Georgia 30336 USA
1-800-AQUASMART |
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